A Study of Tetrathiomolybdate (TM) Plus Capecitabine for Triple Negative Breast Cancer

This study is looking at whether adding tetrathiomolybdate (TM) to standard treatments like capecitabine and pembrolizumab can help patients with triple negative breast cancer that has residual disease (cancer cells remaining after initial treatment). Tetrathiomolybdate is a drug that lowers copper in the body. You may be able to join if you are between 18 and 80 years old, have triple negative breast cancer (meaning your cancer is negative for estrogen receptor, progesterone receptor, and HER2), and have completed at least 6 cycles of chemotherapy before surgery. The study aims to first check the safety of this combination, and then see if adding tetrathiomolybdate improves how long people live without their cancer returning in a distant part of the body. The study is currently unclear on its recruitment status and plans to enroll 204 participants.

Study design
This study has two parts: a Phase 1b to check safety, followed by a randomized Phase 2 study. The Phase 2 part will compare tetrathiomolybdate plus capecitabine versus capecitabine alone.
What's involved
Participants in Phase 1b will receive tetrathiomolybdate, capecitabine for 6 months, and pembrolizumab. Tetrathiomolybdate will continue for a total of 3 years.
Compensation
Not stated in the trial record.
Follow-up
The study will measure safety for 3 years and distant relapse-free survival for 10 years.

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NCT06134375

A Study of Tetrathiomolybdate (TM) Plus Capecitabine

Recruiting
PHASE1Ages 18–80InterventionalTreatment
Dartmouth-Hitchcock Medical Center
~204 participants
Updated 2026-04-20 on ClinicalTrials.gov
What's tested:TetrathiomolybdateCapecitabinePembrolizumab

At a glance

Recruiting sites
2 of 3 listed sites are recruiting right now
RecruitingSuspended, closed, or not yet open
What they're measuring
Phase 1b: To establish the safety of the combination of adjuvant tetrathiomolybdate with capecitabine and pembrolizumab by the number of dose limiting toxicities
Measured over 3 years
+1 more outcome measured
Triple Negative Breast Cancer
Residual Disease

NCT06134375

Where you'd take part

This study runs at 3 sites. They're the same protocol — you choose where, and that choice sets who your contact draft is addressed to.

  • Dartmouth Hitchcock Medical Center

    Lebanon, New Hampshirestudy coordinator listed

    Recruiting

  • NYU Langone perimutter Cancer Center

    New York, New Yorkstudy coordinator listed

    Recruiting

  • Indiana University Simon Cancer Center

    Indianapolis, Indianano site contact published

    Not yet recruiting

Sites open and close at different times, so the status above is per site — it can differ from the study's overall status.

  • Linda Vahdat, MD · PRINCIPAL_INVESTIGATOR · Study Principal Investigator

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Eligibility criteria

Inclusion

hemoglobin \>10mg/dL
absolute neutrophil count \>1,500/ µL
platelets \>100,000/µL
total bilirubin \<1.5 x normal institutional limits
AST (SGOT)/ALT (SGPT) \<1.5 X institutional upper limit of normal 11. Antiresorptive therapy and denosumab may be administered. 12. Patients must be on stable medical therapy for at least 2 weeks if they are being treated medically for their chemotherapy induced peripheral neuropathy. 13. The effects of TM on the developing human fetus are unknown. For this reason, women of childbearing potential and men must agree to use adequate contraception (hormonal or barrier method of birth control; abstinence) prior to study entry and for the duration of study participation. Should a woman become pregnant or suspect she is pregnant while participating in this study, she should inform her treating physician immediately. 14. Ability to understand and the willingness to sign a written informed consent document. 15. Normal B12 levels.
  • Phase 1b: To establish the safety of the combination of adjuvant tetrathiomolybdate with capecitabine and pembrolizumab by the number of dose limiting toxicities3 years

    To establish the safety of the combination of adjuvant tetrathiomolybdate with capecitabine and pembrolizumab administered to patients with triple negative breast cancer after completion of neoadjuvant chemotherapy and with a non-pCR (RCB 2, 3) after standard surgery. The safe dose is defined as the dose level at which no more than 1 out of 6 patients has a DLT on Cycle 1. A dose limiting toxicity (DLT) is defined as a grade 3 hematologic toxicity or non-hematologic toxicity excluding hand foot syndrome, mucositis, or diarrhea. The DLT window is 4 weeks. All toxicities will be summarized.

  • Phase 2: Distant relapse-free survival (DRFS) between TM and capecitabine versus capecitabine as measured with the STEEP system10 years

    The primary endpoint of this study is distant relapse-free survival (DRFS) between TM and capecitabine versus capecitabine. The continued use of adjuvant immunotherapy with pembrolizumab is left to investigator choice. DRFS is defined in accordance with the STEEP system. This definition of DRFS, includes the following as events: distant recurrence, death from breast cancer, death from non-breast cancer or unknown causes, or any second primary invasive cancer. DRFS will be compared by arm in each of the two RCB groups separately using time-to-event analytic methods such as the log-rank test and Cox regression.